Experiments of nitrogen non-premixed suppression of gasoline-air mixture explosion
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摘要: 依靠激波管可视化实验台架，完成了油气爆炸的氮气非预混抑制实验，获得了火焰前锋在氮气非预混段内衰减、熄灭过程的高速摄影照片。通过对实验数据和高速摄影照片的分析，讨论了油气爆炸氮气非预混抑制过程的超压特性和火焰行为。结果表明，采用氮气非预混手段能显著降低油气爆炸过程的超压与超压上升速率。油气爆炸的氮气非预混抑爆过程经历了惯性相持期、抑制衰减期和扩散熄灭期3个阶段。氮气分子作为第三体参与化学反应并携带走高能自由基的能量，促使链式反应向中止链大量发展，这是油气爆炸氮气非预混抑制过程的主要机理。抑制衰减期的火焰由衰减抑制区和核心区火焰构成，火焰与氮气的相互作用主要发生在衰减抑制区内。在抑制衰减期内，火焰速度的衰减可用线性公式描述。Abstract: We carried out experiments of suppressing the gasoline-air explosion by non-premixed nitrogen using the visualization experimental bench and a high-speed camera to take photos of the flame front extinction to capture the suppression process. Based on the analysis of the experimental data and high-speed taken photos, we examined the overpressure characteristics and the flame behavior of the suppression process. Results from our study show that the suppression by non-premixed nitrogen can significantly reduce the overpressure in the gasoline-air mixture explosion and its rise rate, and in the suppression process three phases are identified: sustained inertia, suppression/attenuation, and diffusion/extinction. The mechanism governing the suppression process is that nitrogen molecules participate in the chemical reaction as a third part and can then absorb energy from the high-energy free radicals so that the main reaction chains are changed to termination chains. The flame in the phase of the suppression/attenuation can be divided into the suppression/attenuation zone (where suppression and attenuation occur) and the core zone. In the phase of suppression and attenuation, the relationship between the flame speed and time can be described by a linear formula.
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图 2 有无氮气非预混抑制时的超压曲线
Figure 2. Curves of overpressure of the explosion with and without suppression by non-premixed nitrogen
图 3 高速摄影仪捕捉到的火焰前锋在氮气中熄灭的过程
Figure 3. Photos of flame front in extinction, captured by high speed camera
图 5 氮气非预混抑爆过程中火焰速度随时间的变化
Figure 5. Variation of the flame speed with time in suppression process
表 1 实验前后激波管内主要气体组分的体积分数
Table 1. Volume fraction of main gas components before and after the experiment
测量条件 φ/% 油气 O2 CO2 CO 实验前 1.61 20.42 0.01 0 实验后 1.19 15.24 2.86 0.89 
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