Volume 44 Issue 4
Apr.  2024
Turn off MathJax
Article Contents
JI Wentao, GUO Xiaoxiao, CHEN Zhitao, CAI Chongchong, WANG Yan. Suppression characteristics and mechanism of polyethylene dust explosion by Mg-Al hydrotalcite[J]. Explosion And Shock Waves, 2024, 44(4): 045401. doi: 10.11883/bzycj-2023-0263
Citation: JI Wentao, GUO Xiaoxiao, CHEN Zhitao, CAI Chongchong, WANG Yan. Suppression characteristics and mechanism of polyethylene dust explosion by Mg-Al hydrotalcite[J]. Explosion And Shock Waves, 2024, 44(4): 045401. doi: 10.11883/bzycj-2023-0263

Suppression characteristics and mechanism of polyethylene dust explosion by Mg-Al hydrotalcite

doi: 10.11883/bzycj-2023-0263
  • Received Date: 2023-08-02
  • Rev Recd Date: 2023-10-30
  • Available Online: 2024-01-17
  • Publish Date: 2024-04-07
  • In order to find a new, clean and efficient inhibitor of PE dust explosion, the Mg-Al hydrotalcite was used to inhibit PE dust explosion by using standard 20 L spherical explosion test system and minimum ignition temperature test system of dust cloud. The inhibition properties of Mg-Al hydrotalcite for PE dust explosion are analyzed from the aspects of explosion overpressure and minimum ignition temperature, and are compared with aluminum hydroxide and magnesium hydroxide. The results showed that the inhibition effect of Mg-Al hydrotalcite on explosion overpressure and minimum ignition temperature of polyethylene dust is superior to that of aluminum hydroxide and magnesium hydroxide. In terms of explosion overpressure, when the inhibition ratio is 2, Mg-Al hydrotalcite can completely inhibit the explosion of polyethylene dust, while the inhibition ratios required for aluminum hydroxide and magnesium hydroxide to achieve complete explosion suppression of polyethylene are 4 and 5 respectively. With the increase of inhibition ratio, the maximum explosion pressure rise rate of polyethylene dust decreased. The inhibition effect of Mg-Al hydrotalcite on the explosion pressure rise rate of polyethylene dust is also better than that of aluminum hydroxide and magnesium hydroxide. In terms of minimum ignition temperature, when the inhibition ratio was 1, Mg-Al hydrotalcite increased the minimum ignition temperature of polyethylene dust to 710 ℃, which was 290 ℃ higher than that of pure polyethylene dust. Under the same conditions, aluminum hydroxide and magnesium hydroxide can increase the minimum ignition temperature of polyethylene dust by 260 ℃ and 250 ℃ respectively. Therefore, the inhibition effect of Mg-Al hydrotalcite on the minimum ignition temperature of polyethylene is also greater than that of aluminum hydroxide and magnesium hydroxide. In addition, the inhibition mechanism of Mg-Al hydrotalcite on polyethylene dust explosion was analyzed based on its pyrolysis characteristics and infrared spectra.The physical effect is mainly realized by absorbing heat from the reaction system and diluting the oxygen concentration. The chemical action is mainly achieved by the pyrolysis products carbon dioxide and water participating in and blocking the polyethylene explosion chain reaction.
  • loading
  • [1]
    MAZUR K, JAKUBOWSKA P, ROMAÑSKA P, et al. Green high density polyethylene (HDPE) reinforced with basalt fiber and agricultural fillers for technical applications [J]. Composites Part B: Engineering, 2020, 202: 108399. DOI: 10.10.1016/j.compositesb.2020.108399.
    [2]
    OKHOTNIKOVA E S, GANEEVA Y M, FROLOV I N, et al. Structural characterization and application of bitumen modified by recycled polyethylenes [J]. Construction and Building Materials, 2022, 316: 126118. DOI: 10.1016/j.conbuildmat.2021.126118.
    [3]
    SAHI S, DJIDJELLI H, BOUKERROU A. Study of the properties and biodegradability of the native and plasticized corn flour-filled low density polyethylene composites for food packaging applications [J]. Materials Today: Proceedings, 2021, 36: 67–73. DOI: 10.1016/j.matpr.2020.05.317.
    [4]
    马龙. 全球聚乙烯供需分析与预测 [J]. 世界石油工业, 2021, 28(4): 58–65.

    MA L. Anaysis and forecast of global polyethylene supply and demand [J]. World Petroleum Industry, 2021, 28(4): 58–65.
    [5]
    马冉, 高建村, 杨凯, 等. 聚乙烯粉尘爆炸研究进展 [J]. 中国粉体技术, 2017, 23(6): 59–63. DOI: CNKI:SUN:FTJS.0.2017-06-012.

    MA R, GAO J C, YANG K, et al. Progress research on polyethylene dust explosion [J]. China Power Science and Technology, 2017, 23(6): 59–63. DOI: CNKI:SUN:FTJS.0.2017-06-012.
    [6]
    YANG K, CAO J, ZHAO Y, et al. Inerting effect of N2 on explosion of LDPE dust/ethylene hybrid mixtures [J]. Journal of Loss Prevention in the Process Industries, 2021, 70: 104431. DOI: 10.1016/j.jlp.2021.104431.
    [7]
    GAN B, GAO W, JIANG H, et al. Flame propagation behaviors and temperature characteristics in polyethylene dust explosions [J]. Powder Technology, 2018, 328: 345–357. DOI: 10.1016/j.powtec.2018.01.061.
    [8]
    PANG L, MA R, HU S, et al. Flame propagation of local LDPE dust cloud in a semi-open duct [J]. Experimental Thermal and Fluid Science, 2019, 101: 209–216. DOI: 10.1016/j.expthermflusci.2018.10.025.
    [9]
    庞磊, 马冉, 高建村, 等. 粉尘云浓度对 HDPE粉尘云最低着火温度的影响 [J]. 中国安全生产科学技术, 2017, 13(5): 5–9. DOI: 10.11731/j.issn.1673-193x.2017.05.001.

    PANG L, MA R, GAO J C, et al. Effect of dust cloud concentration on minimum ignition temperature of HDPE dust cloud [J]. China Safety Science and Technology, 2017, 13(5): 5–9. DOI: 10.11731/j.issn.1673-193x.2017.05.001.
    [10]
    庞磊, 赵钰, 杨凯, 等. 低密度聚乙烯粉尘云爆炸敏感性实验 [J]. 消防科学与技术, 2019, 38(9): 1211–1215. DOI: CNKI:SUN:XFKJ.0.2019-09-004.

    PANG L, ZHAO Y, YANG K, et al. Explosion susceptibility experiment of low-density polyethylene dust cloud [J]. Fire Science and Technology, 2019, 38(9): 1211–1215. DOI: CNKI:SUN:XFKJ.0.2019-09-004.
    [11]
    LIU J, MENG X, YAN K, et al. Study on the effect and mechanism of Ca(H2PO4)2 and CaCO3 powders on inhibiting the explosion of titanium powder [J]. Powder Technology, 2022, 395: 158–167. DOI: 10.1016/j.powtec.2021.09.067.
    [12]
    LU K, CHEN X, LUO Z, et al. The inhibiting effects of sodium carbonate on coal dust deflagration based on thermal methods [J]. Fuel, 2022, 315: 123122. DOI: 10.1016/j.fuel.2021.123122.
    [13]
    ZHAO Q, CHEN X, DAI H, et al. Inhibition of diammonium phosphate on the wheat dust explosion [J]. Powder technology, 2020, 367: 751–761. DOI: 10.1016/j.powtec.2020.04.026.
    [14]
    ZHANG Y, PAN Z, YANG J, et al. Study on the suppression mechanism of (NH4)2CO3 and SiC for polyethylene deflagration based on flame propagation and experimental analysis [J]. Powder Technology, 2022, 399: 117193. DOI: 10.1016/J.POWTEC.2022.117193.
    [15]
    WANG Y, QI Y, PEI B, et al. Suppression of polyethylene dust explosion by sodium bicarbonate [J]. Powder Technology, 2020, 367: 206–212. DOI: 10.1016/j.powtec.2020.03.049.
    [16]
    LIN S, LIU Z, QIAN J, et al. Inertant effects and mechanism of Al(OH)3 powder on polyethylene dust explosions based on flame propagation behavior and thermal analysis [J]. Fire Safety Journal, 2021, 124: 103392. DOI: 10.1016/j.firesaf.2021.103392.
    [17]
    ADDAI E K, GABEL D, KRAUSE U. Experimental investigations of the minimum ignition energy and the minimum ignition temperature of inert and combustible dust cloud mixtures [J]. Journal of Hazardous Materials, 2016, 307: 302–311. DOI: 10.1016/j.jhazmat.2016.01.018.
    [18]
    JIANG H, BI M, LI B, et al. Inhibition evaluation of ABC powder in aluminum dust explosion [J]. Journal of Hazardous Materials, 2019, 361: 273–282. DOI: 10.1016/j.jhazmat.2018.07.045.
    [19]
    SINGHAL A, SKANDAN G, WANG A, et al. On nanoparticle aggregation during vapor phase synthesis [J]. Nanostructured Materials, 1999, 11(4): 545–552. DOI: 10.1016/S0965-9773(99)00343-8.
    [20]
    余明高, 贺涛, 李海涛, 等. 改性高岭土抑爆剂对瓦斯煤尘复合爆炸压力的影响 [J]. 煤炭学报, 2022, 47(1): 348–359. DOI: 10.13225/j.cnki.jccs.yg21.1731.

    YU M G, HE T, LI H T, et al. Influence of modified kaoline inhibitor on the explosion suppression pressure of the methane-coal dust mixture [J]. Journal of China Coal Society, 2022, 47(1): 348–359. DOI: 10.13225/j.cnki.jccs.yg21.1731.
    [21]
    XU S, ZHANG M, LI S Y, et al. The effect of ammonium polyphosphate on the mechanism of phosphorous-containing hydrotalcite synergism of flame retardation of polypropylene [J]. Applied Clay Science, 2020, 185: 105348. DOI: 10.1016/j.clay.2019.105348.
    [22]
    SANTOSA S J, ASTUTI D P. Reusable high performance of calcined Mg/Al hydrotalcite for the removal of Navy Blue and Yellow F3G dyes [J]. Chinese Journal of Chemical Engineering, 2021, 38: 247–254. DOI: 10.1016/j.cjche.2020.08.038.
    [23]
    CHEN J, WANG C, ZHANG Y, et al. Engineering ultrafine NiS cocatalysts as active sites to boost photocatalytic hydrogen production of Mg-Al layered double hydroxide [J]. Applied Surface Science, 2020, 506: 144999. DOI: 10.1016/j.apsusc.2019.144999.
    [24]
    NAKAYAMA H, HATAKEYAMA A, TSUHAKO M. Encapsulation of nucleotides and DNA into Mg-Al layered double hydroxide [J]. International journal of pharmaceutics, 2010, 393(1/2): 105–112. DOI: 10.1016/j.ijpharm.2010.04.013.
    [25]
    PÉREZ A, OTERO R, ESQUINAS A R, et al. Potential use of modified hydrotalcites as adsorbent of bentazon and metazachlor [J]. Applied clay science, 2017, 141: 300–307. DOI: 10.1016/j.clay.2017.03.007.
    [26]
    GUALANDI I, TESSAROLO M, MARIANI F, et al. Layered double hydroxide-modified organic electrochemical transistor for glucose and lactate biosensing [J]. Sensors, 2020, 20(12): 3453. DOI: 10.3390/s20123453.
    [27]
    ZHOU X, MU X, CAI W, et al. Design of hierarchical NiCo-LDH@PZS hollow dodecahedron architecture and application in high-performance epoxy resin with excellent fire safety [J]. ACS Applied Materials & Interfaces, 2019, 11(44): 41736–41749. DOI: 10.1021/acsami.9b16482.
    [28]
    QIAN Y, QIAO P, LI L, et al. Hydrothermal synthesis of lanthanum-doped MgAl-layered double hydroxide/graphene oxide hybrid and its application as flame retardant for thermoplastic polyurethane [J]. Advances in Polymer Technology, 2020, 2020(3): 1–10. DOI: 10.1155/2020/1018093.
    [29]
    HUANG C, CHEN X, YUAN B, et al. Suppression of wood dust explosion by ultrafine magnesium hydroxide [J]. Journal of hazardous materials, 2019, 378: 120723. DOI: 10.1016/j.jhazmat.2019.05.116.
    [30]
    ZHANG L, BIAN Y, KUAI D. Preparation and flame retardant property of nano-aluminum hydroxide foam for preventing spontaneous coal combustion [J]. Fuel, 2021, 304: 121494. DOI: 10.1016/J.FUEL.2021.121494.
    [31]
    WANG Z, MENG X, YAN K, et al. Inhibition effects of Al(OH)3 and Mg(OH)2 on Al-Mg alloy dust explosion [J]. Journal of Loss Prevention in the Process Industries, 2020, 66: 104206. DOI: 10.1016/j.jlp.2020.104206.
    [32]
    WANG Z, MENG X, YAN K, et al. Study on the inhibition of Al-Mg alloy dust explosion by modified Mg(OH)2 [J]. Powder Technology, 2021, 384: 284–296. DOI: 10.1016/j.powtec.2021.02.037.
    [33]
    WANG X, DAI H, LIANG G, et al. Flame propagation characteristics of mixed pulverized coal at the atmosphere of gasification [J]. Fuel, 2021, 300: 120954. DOI: 10.1016/J.FUEL.2021.120954.
    [34]
    WANG Q, SUN Y, JIANG J, et al. Inhibiting effects of gas-particle mixtures containing CO2, Mg(OH)2 particles, and NH4H2PO4 particles on methane explosion in a 20-L closed vessel [J]. Journal of Loss Prevention in the Process Industries, 2020, 64: 104082. DOI: 10.1016/j.jlp.2020.104082.
    [35]
    YAHYAOUI R, JIMENEZ P E S, MAQUEDA L A P, et al. Synthesis, characterization and combined kinetic analysis of thermal decomposition of hydrotalcite (Mg6Al2(OH)16CO3·4H2O) [J]. Thermochimica Acta, 2018, 667: 177–184. DOI: 10.1016/j.tca.2018.07.025.
    [36]
    国家技术监督局. 粉尘云最大爆炸压力和最大爆炸压力上升速率测定方法: GB/T 16426—1996 [S]. 北京: 中国标准出版社, 1996.
    [37]
    国家技术监督局. 粉尘云最低着火温度测定方法: GB/T 16429—1996 [S]. 北京: 中国标准出版社, 1997.
    [38]
    Determination of explosion characteristics of dust clouds: Part 3: Determination of the lower explosion limit LEL of dust clouds: EN14034-3[S]. England: The Standards Policy and Strategy Committee, 2006: 5-16.
    [39]
    邹瑜. 水滑石类功能材料的特性分析及其阻燃应用 [J]. 硅酸盐通报, 2020, 39(12): 4034–4042. DOI: 10.16552/j.cnki.issn1001-1625.2020.12.041.

    ZOU Y. Characteristic analysis of layered double hydroxides functional materials and its flame retardant application [J]. Bulletion of the Chinese Ceramic society, 2020, 39(12): 4034–4042. DOI: 10.16552/j.cnki.issn1001-1625.2020.12.041.
    [40]
    甘波. 乙烯/聚乙烯混合爆炸火焰传播机理研究[D]. 大连:大连理工大学, 2019. DOI: 10.26991/d.cnki.gdllu.2019.001235.
    [41]
    李运芝, 袁俊明, 王保民. 粉尘爆炸研究进展[J]. 太原师范学院学报(自然科学版), 2004(2): 79–82. DOI: 10.3969/j.issn.1672-2027.2004.02.024.

    LI Y Z, YUAN J M, WANG B M. Developing of dust exploding study[J]. Journal of Taiyuan Normal University (Natural Science Edition), 2004(2): 79–82. DOI: 10.3969/j.issn.1672-2027.2004.02.024.
    [42]
    袁长高. 轻烃对聚乙烯装置燃爆危险的影响研究[D]. 青岛:中国石油大学(华东), 2015.
    [43]
    JIN X, GU X, CHEN C, et al. The fire performance of polylactic acid containing a novel intumescent flame retardant and intercalated layered double hydroxides [J]. Journal of Materials Science, 2017, 52(20): 12235–12250. DOI: 10.1007/s10853-017-1354-5.
    [44]
    鲍艳, 唐培, 刘超. 水滑石的制备及其阻燃性能研究进展 [J]. 精细化工, 2022, 39(1): 24–33. DOI: 10.13550/j.jxhg.20210696.

    BAO Y, TANG P, LIU C. Research progress on preparation and flame retardant properties of layered double hydroxides [J]. Fine Chemicals, 2022, 39(1): 24–33. DOI: 10.13550/j. jxhg. 20210696. DOI: 10.13550/j.jxhg.20210696.
    [45]
    DU J Z, JIN L, ZENG H Y, et al. Facile preparation of an efficient flame retardant and its application in ethylene vinyl acetate [J]. Applied Clay Science, 2019, 168: 96–105. DOI: 10.1016/j.clay.2018. 11. 004. DOI: 10.1016/j.clay.2018.11.004.
    [46]
    XU S, LI S Y, ZHANG M, et al. Fabrication of green alginate-based and layered double hydroxides flame retardant for enhancing the fire retardancy properties of polypropylene [J]. Carbohydrate Polymers, 2020, 234: 115891. DOI: 10.1016/j.carbpol.2020.115891.
    [47]
    ZHANG L, GUO D, TANTAI X, et al. Synthesis of three-dimensional hierarchical flower-like Mg-Al layered double hydroxides with excellent adsorption performance for organic anionic dyes [J]. Transactions of Tianjin University, 2021, 27(5): 394–408. DOI: 10.1007/s12209-020-00249-5.
    [48]
    SHAN R, YAN L, YANG Y, et al. Highly efficient removal of three red dyes by adsorption onto Mg-Al-layered double hydroxide [J]. Journal of Industrial and Engineering Chemistry, 2015, 21: 561–568. DOI: 10.1016/j.jiec.2014.03.019.
    [49]
    WEI P R, CHENG S H, LIAO W N, et al. Synthesis of chitosan-coated near-infrared layered double hydroxide nanoparticles for in vivo optical imaging [J]. Journal of Materials Chemistry, 2012, 22(12): 5503–5513. DOI: 10.1039/C2JM16447G.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(13)

    Article Metrics

    Article views (61) PDF downloads(13) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return