Abstract: The Mie-Grüneisen mixture model is conveniently used in the multi-component problem with Mie-Grüneisen EOS (equation of states). In the Mie-Grüneisen EOS, the isentropic and Hugoniot curves are two typical reference states curves. However, the curves of these two reference states contain singularity points and cause difficulty when the interface is treated by volume fraction, which is accustomed used as a color function in traditional model. The difficulty lies in that the volume fraction model produces fragments of fluid volumes near the interface due to its diffused style, these volume fragments may encounter the singularity points and make the sound velocity abnormally high at the interface in some isentropic reference curves. On the other side, the singularity points may cause the sound velocity negative for some Hugoniot reference states and interrupt the calculation. To avoid volumes fragments near the interface area, the volume fraction is replaced by mass fraction, and the relative volume is defined by the reciprocal of proportional density of fluid component. This definition makes the relative volume no less than which of fluids mixture. Thanks to the reconstructed relative volume, the sound velocity forms a trough shape at the interface and does not cause high peak value. Moreover, some equations in Mie-Grüneisen mixture model contains the derivatives items of reference states parameters, when these items are defined as weighted average mixture at the interface, they often become negative if weighted average of mass fraction are directly used. To prevent the negative value at the interface, the reference states are optimized at the interface. Numerical examples show that the mass fraction has tiny improvement on the accuracy of results, it makes the sound velocity steady on the isentropic reference states of medium and spend less time steps than volume fraction model. And the mass fraction can be used to correct the negative sound velocity in Hugoniot reference states. Then the calculation is kept smooth and accurate.