Study on the variation law of explosion strength parameters in the hybrid explosion of hydrogen and titanium dust
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摘要: 在钛基固态金属储氢技术应用及钛金属制品生产加工过程中极易形成氢气/钛粉两相体系,具有较高的爆炸风险。为研究氢气/钛粉两相体系爆炸特性,本文采用20 L球形爆炸装置,在0%~30%的氢气浓度和100~700 g/m³的钛粉浓度范围内,对氢气/钛粉两相体系爆炸强度参数变化规律进行了研究,并结合爆炸产物,分析了爆炸强度参数变化规律形成机理。结果表明,氢气的存在会显著影响钛粉爆炸强度。总体上,在100~700 g/m³钛粉浓度范围内,其爆炸压力Pex随氢气浓度的增大先减小后增大再减小,当氢气浓度为4%时降至最低,当氢气浓度为29%时增至最大;其爆炸压力上升速率(dP/dt)ex随氢气浓度增大先减小后增大,当氢气浓度为4%时降至最低,当氢气浓度为30%时增至最大。氢气/钛粉两相体系最大爆炸压力Pmax同样随氢气浓度的增大先减小后增大再减小,在氢气浓度为4%时降至最低,在氢气浓度为29%时达到峰值;最大爆炸压力上升速率(dP/dt)max随氢气浓度的增大先减小后增大,当氢气浓度为4%时达到最小值,随后持续上升,在氢气浓度为30%时达到峰值。爆炸产物分析结果表明,低浓度氢气会导致或加剧钛粉的不完全氧化反应,进而导致钛粉爆炸压力Pex和爆炸压力上升速率(dP/dt)ex的降低;当氢气浓度增至临界值后,氢气的自主燃烧将促进钛粉与氮气之间的反应,并促使两相体系爆炸过程由异相燃烧向均相燃烧转变,进而导致钛粉爆炸压力Pex和爆炸压力上升速率(dP/dt)ex的增大。
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关键词:
Abstract: The hydrogen/titanium powder two-phase system readily forms during the application of titanium-based solid-state hydrogen storage technology and the production and processing of titanium metal products, posing a high explosion risk. To investigate the explosion characteristics of this hydrogen/titanium powder two-phase system, this study employed a 20 L spherical explosion apparatus. Within a range of hydrogen concentrations from 0% to 30% and titanium powder concentrations from 100 to 700 g/m³, the variation patterns of explosion intensity parameters were examined. Combined with analysis of the explosion products, the formation mechanisms underlying these parameter variations were elucidated.The results indicate that the presence of hydrogen significantly affects the explosion intensity of titanium powder.Overall, within the titanium powder concentration range of 100-700 g/m³, the explosion pressure<italic>P</italic>ex first decreases, then increases, and finally decreases again as hydrogen concentration rises. It reaches its minimum at a hydrogen concentration of 4% and its maximum at 29%. The rate of increase in explosion pressure (d<italic>P</italic>/d<italic>t</italic>)ex first decreases then increases with rising hydrogen concentration. It reaches its minimum at 4% hydrogen concentration and its maximum at 30% hydrogen concentration.The maximum explosion pressure <italic>P</italic>max of the hydrogen/titanium powder two-phase system also decreases initially, then increases, and finally decreases again with increasing hydrogen concentration. It reaches its lowest point at a hydrogen concentration of 4% and peaks at 29%. The maximum explosion pressure rise rate (d<italic>P</italic>/d<italic>t</italic>)max first decreases then increases with increasing hydrogen concentration. It reaches its minimum at 4% hydrogen concentration and subsequently rises continuously, peaking at 30% hydrogen concentration.Analysis of explosion products indicates that low hydrogen concentrations cause or exacerbate incomplete oxidation reactions in titanium powder, thereby reducing both the explosion pressure <italic>P</italic>ex and the explosion pressure rise rate (d<italic>P</italic>/d<italic>t</italic>)ex.When the hydrogen concentration increases to the critical value, the spontaneous combustion of hydrogen promotes the reaction between titanium powder and nitrogen, causing the two-phase system's explosion process to transition from heterogeneous combustion to homogeneous combustion. This transition leads to an increase in both the explosion pressure <italic>P</italic>ex of the titanium powder and the rate of pressure rise (d<italic>P</italic>/d<italic>t</italic>)ex.-
Key words:
- titanium powder /
- hydrogen /
- two-phase system /
- explosion pressure /
- explosion pressure rise rate
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